The Russians advanced to play either Italy or the Czech Republic in November's final after Makarova and Vesnina prevailed over the Slovak duo of Dominika Cibulkova and Daniela Hantuchova 4-6, 6-3, 6-1, competing Russia's desperate comeback from a 2-0 deficit.
But the Russians they stormed back in Sunday's reverse singles match-ups.
Kirilenko first prevented a Slovakian sweep with a 7-5, 6-1 triumph over Cibulkova and Makarova continued the rally a with a 6-3, 4-6, 6-4 win over Hantuchova, setting up the decisive doubles showdown.
Russia's opponent in the Fed Cup final will be determined Monday when Italy and the Czech Republic complete their rain-delayed semifinal in Palermo, Italy.
The Italians hold a 2-1 lead in that series.