The CD is to go on sale Dec. 3.
"The album celebrates the strong bond that has been in place between the two artists ever since Babyface and Toni's duet on her smash 1992 debut, 'Give U My Heart,' which was co-written and co-produced by Babyface [from the 'Boomerang' movie soundtrack]," a news release said.
"Hurt You," the first single from their new album, is on the radio and iTunes now.
Notable deaths of 2014 [PHOTOS]
Jason Aldean to extend Burn It Down Tour