Miller and Boldin will be on the Red Carpet and during the live show on CBS from the Staples Center in Los Angeles, the NFL announced Friday.
Miller and Boldin will introduce a musical performance by Carrie Underwood and Sam Hunt. Underwood sings the theme song for "Sunday Night Football."
Miller led a Broncos defense that recorded seven sacks in the 24-10 upset win against the Carolina Panthers last Sunday night at Levi's Stadium in Santa Clara, Calif. Miller had six tackles, 2.5 sacks, two quarterback hits and two forced fumbles that led to points.
Boldin, wide receiver of the San Francisco 49ers, was named the Man of the Year on the eve of the Super Bowl as recognition for his excellence on and off the field.
Boldin's foundation has awarded 13 four-year college scholarships through the "Q81" fund. Boldin will become a free agent on March 9 when the new league year starts.