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Police said Henio had paint on his upper lip and they recognized the smell of spray paint.
The suspect, who was described by police as "extremely jittery," told officers he knew he was trespassing and wanted to go to New Mexico, the arrest report said.
Henio, who allegedly tried to resist being handcuffed, was arrested and charged with possession of a vapor releasing substance, possession of drug paraphernalia and trespassing. He was taken to the Mesa City Jail.