Brad Pitt and Angelina Jolie shocked the celerity world when they announced their divorce in September after they reportedly began dating on the set of Mr. and Mrs. Smith in 2004. They married in 2014 and are parents to six children -- three biological and three adopted.
Here's a list of other celebrity couples who called it quits in 2016.
3. Mariah Carey and James Packer
6. Jennifer Lopez and Casper Smart
7. Drew Barrymore and Will Kopelman