The 49-year-old actress shared a photo with the 54-year-old Kering CEO on Instagram, writing, "#nofilter #love #amor." She and Pinault are all smiles as they embrace in the picture.
Hayek and Pinault are spending time in the businessman's home country of France. The actress previously told fans she is in Dinard, a coastal region in the west of France.
Hayek and Pinault married in Paris in 2009 and share an 8-year-old daughter, Valentina. The actress recently told Red magazine she considers her marriage and family her greatest achievement.
"A good marriage, full of love, is my biggest accomplishment," she said. "Home is where my husband is. He is home. Everything outside of the family nucleus is an adventure that you're living together."
"I try to be with Valentina as much as possible, even when I'm working," the star added. "It takes a lot of work and mummies are very tired because most of us work and life is exhausting, especially if you're an older mom like me, but you have to make the effort."
Hayek will next appear in the comedy Drunk Parents with Alec Baldwin. She is also slated to voice a character in the animated movie Sausage Party and star in How to Be a Latin Lover with Kristen Bell.