The 38-year-old mother of six and her partner, Brad Pitt, showed up to the BAFTAs wearing coordinating tuxedos.
Pitt opted for a classic Valentino suit. Jolie, meanwhile, wore almost exactly the same thing, a Saint Laurent tuxedo suit, though she left collar open and bow tie undone.
Pitt's, who produced and starred in 12 Years a Slave, picked up a BAFTA Award for Best Film.
He and Jolie recently returned from Australia with their six children. Jolie had spent several months down under directing the World War II film, Unbroken.
[Express UK, Just Jared]
Celebrity Families of 2014 [PHOTOS]