After arriving fashionably late to the event, the 54-year-old singer/songwriter walked the red carpet in a Givenchy ensemble consisting of a studded black and grey tartan jacket secured with a studded black belt, a fishnet mini, black tights and pink heels.
The "Give Me All Your Lovin'" singer accessorized her heavy metal outfit with a pitch black wig, a metal choker necklace and a lot of silver bling.
Madonna's outfit was conceived by Riccardo Tisci from Givenchy Haute Coutoure, E! News reported.
2014: The Year in Music [PHOTOS]