However, much to her surprise, Pitt showed up in her dressing room after the performance and asked if he could take a picture with her.
"He was like 'Could I have a picture with you?' and I was like 'Could I have a picture with YOU?'," Gomez told Ellen, adding that his kids were fans of her show.
Ellen proceeded to question Gomez about her life without Bieber, and whether she was happy.
"I met Brad Pitt," she responded. "I'm great!"
Notable deaths of 2014 [PHOTOS]