Clad in a black-and-silver Reem Acra number, the 46-year-old actress talked cars, clothes and James Bond with the microphone draped over her shoulder (we can only assume there was no place to hide it in her neckline).
Leno didn't mention Berry's "Tonight Show" look, but he did praise the Bond-inspired Versace gown she wore to the Oscars last month.
"I wanted to go to the Oscars looking like a Bond girl," she told Leno. "I felt like I was -- you'll appreciate this -- wearing a Ferrari."
"Can you drive a stick shift? I'm just curious," Leno replied.
Berry was on the show to promote her current film "The Call," but the actress did confirm she would reprise her role as Storm in the next "X-Men" film.
Watch the interview below: