Hollande met with Sheik Ahmad Moaz al-Khatib, head of the National Coalition of Syrian Revolutionary and Opposition Forces, The New York Times reported. The coalition plans to set up a provisional government in opposition to President Bashar Assad.
Khatib said he plans to name Mounzir Makhous as the ambassador. Makhous, like Assad, is an Alawite, a minority sect within Islam.
The Syrian Embassy in Paris remains the property of the Damascus government, so Hollande said France would find an office for Makhous.
Hollande also said at a foreign ministers meeting Monday he would urge the European Union to help arm the Syrian opposition.