Cooney connected on 5-of-8 3-point tries and Tyler Ennis added 20 points to help the unbeaten Orange (12-0) rally from an 18-point, first-half deficit at the Carrier Dome.
C.J. Fair provided 17 points and six rebounds as Syracuse dealt Villanova its first defeat of the season in a battle of former Big East rivals.
James Bell pumped in 25 points, including six 3-pointers for the Wildcats (11-1), who shot only 38 percent from the field for the game despite starting strongly.
Celebrity Couples of 2014 [PHOTOS]