Pitcher Joe Savery (2-0) then laid down a sacrifice bunt, sending Rollins to second, and Young's single to shallow right field sent him home with the game-winning run, earning the Phillies an interleague double-header split.
Philadelphia lost the first contest 5-4 in 11 frames.
John Mayberry provided the Phillies' only other run with a score-tying solo homer in the seventh.
Gordon Beckham's sacrifice fly in the fifth gave the White Sox their only run in the contest.
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