R.A. Ramirez (1-0) earned the victory, yielding three runs on four hits while striking out four over four innings.
Spain was led by Barbaro Canizares, who belted a two-run homer.
Engel Beltre also went deep and Eddie Morlan (0-1) was tagged with the loss, surrendering three runs on three hits over three-plus frames.
Both Venezuela and Spain had earlier been eliminated from Pool C contention.
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