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Chemists learn to yank some chemical bonds

DURHAM, N.C., March 14 (UPI) -- Duke University chemists, using a chain of molecules as an infinitesimal lanyard, have found they can speed a complex chemical reaction.

The unusual manipulative technique used on a chemical bond about to break can reveal previously unknown details about the evolution of such two-step bond reactions, said Duke Assistant Professor Stephen Craig. It might ultimately aid efforts to develop new kinds of polymers that can "heal" themselves after tearing, he said.

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Craig, doctoral student Farrell Kersey and former graduate student Wayne Yount described their discoveries in a research paper published online this month in the Journal of the American Chemical Society.

The research was funded by the National Science Foundation.

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