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Police spokeswoman Cpl. Tracey Knight confirmed Monday that Officer W. Figeuroa used pepper spray on the passing motorcyclists and documented the incident in a report.
Knight did not disclose the reason Figeuroa gave for discharging his pepper spray.
Figeuroa has been placed on administrative duties pending the outcome of an investigation, the department said.
A spokesman for ambulance service Medstar said five people were treated at the scene for pepper spray exposure, and one man was hospitalized with minor injuries.