The New Mexico-set show's co-star Anna Gunn earned an Emmy for Outstanding Supporting Actress in a Drama Series earlier in the evening.
Gunn plays Skyler White whose husband Walter, played by Bryan Cranston, turns to drug dealing to support his family when he learns he is terminally ill. The series is now in its fifth and final season.
The Outstanding Comedy Series prize went to the sitcom "Modern Family" for the fourth consecutive year.
Celebrity Families of 2014 [PHOTOS]