Timberlake is seen on the cover of People magazine jumping for joy while Biel sits nearby, smiling and wearing a billowy pink wedding gown.
The couple married at the Borgo Egnazia resort in southern Italy Oct. 19 after dating about five years.
"It was a really special evening," Timberlake told People, adding the song with which he serenaded his new wife was "an original piece I wrote specifically for the evening and for her."
"It was a total fantasy experience," said Biel.
Celebrity Families of 2014 [PHOTOS]