Summit Entertainment and Lionsgate said Ray Stevenson and Mekhi Phifer also have joined the cast of the movie, which started shooting Monday.
The ensemble includes Theo James, Maggie Q, Jai Courtney, Miles Teller, Zoe Kravitz, Ansel Elgort, Ben Lloyd-Hughes, Ben Lamb, Christian Madsen and Amy Newbold.
The film, a futuristic action adventure is based on author Veronica Roth's best-selling young adult novel, is due in theaters March 21, 2014.
Neil Burger is directing the movie from a script by Vanessa Taylor.
Celebrity Couples of 2014 [PHOTOS]