MyMemory.com, in an online survey, gave site visitors a chance to vote after being shown a selection of celebrity photographs from which to choose, Britain's The Independent reported Tuesday.
Taylor topped Jennifer Aniston and David Beckham, who ranked second and third respectively, said Rebecca Huggler, co-Founder of MyMemory.com which carried out the informal survey.
"It was very interesting to see a member of Hollywood Royalty, Elizabeth Taylor, clinch the top spot as the most photogenic celebrity of all time; but I think this proves that she will forever be remembered for her timeless beauty," Huggler said.
"Photographs are a huge part of our relationship with celebrities, and with this study we were interested to see which celebrities the British public believe look the best behind the lens."
Rounding out the top 10 on MyMemory's list were Megan Fox at number 4 followed by Audrey Hepburn, Marlon Brando, Angelina Jolie, Marilyn Monroe, Sophia Loren and James Dean at number 10, Britain's The Telegraph reported.