Aniston and Pitt were still married when Pitt and Jolie made the 2005 film "Mr. and Mrs. Smith" together. Jolie has said it was on the set of that movie that she and Pitt started falling in love. They now have six children together.

Aniston and Pitt were married from 2000 to 2005.

"There was stuff printed there that was definitely from a time when I was unaware that it was happening," People.com said Aniston told Vogue for the magazine's December issue, referring to previous statements Jolie had made. "I felt those details were a little inappropriate to discuss. ... That stuff about how she couldn't wait to get to work every day? That was really uncool."